What Is Oxy Desulfurization?


The CoMo hydrogenation catalysts converts any remaining sulfur species exiting the Claus section to H2S before entering the amine tail gas section for final treatment.

Which catalyst is used in hydrodesulfurization?

Ruthenium disulfide (RuS2) appears to be the single most active catalyst, but binary combinations of cobalt and molybdenum are also highly active. In practice, most HDS units in petroleum refineries use catalysts based on cobalt-modified molybdenum disulfide (MoS2) together with smaller amounts of other metals.

What catalyst is used in hydrotreating?

However, metal oxides, that is, alumina-supported metal sulfides are, by far, the most utilized catalysts for hydrotreating. They possess a lower cost, higher resistance to impurities typically present in waste feedstock and allow co-hydroprocessing of plant lipids and petroleum feeds in existing refinery facilities.

What is the difference between hydrotreating and hydrocracking?

The key difference between hydrocracking and hydrotreating is that hydrocracking includes the conversion of high boiling constituents into low boiling constituents, whereas hydrotreating includes the removal of oxygen and other heteroatoms. Hydrocracking and hydrotreating are useful processes in petroleum oil refining.

Why do we sulfide catalyst?

Hydrogen sulfide, which serves as the sulfiding medium, reacts sulfur with the surface of the metallic catalyst. Metal in the catalyst gives up oxygen during the process and combines with hydrogen to form water . Sulfur replaces oxygen on the catalyst.


How is hydrotreating done?

Hydrogen processes, commonly known as hydrotreating, are the most common processes for removing sulfur and nitrogen impurities. The oil is combined with high-purity hydrogen, vapourized, and then passed over a catalyst such as tungsten, nickel, or a mixture of cobalt and molybdenum oxides supported on an alumina base.

Why is sulphur removed from crude oil?

The purpose of removing the sulfur is to reduce the SO2 emissions. The HDS process involves catalytic treatment with hydrogen to convert the various sulfur compounds present to hydrogen sulfide.

Why sulphur is removed from fuel?

The automobile manufacturers demand removal of sulfur containing compounds out of petroleum in order to reduce overall emissions from vehicles. This is because sulfur compounds poison the catalytic converters that reduce particulates and NOx emissions.

What is hydrodesulfurization used for?

Hydrodesulphurization (HDS) is a catalytic process typically used in the Oil & Gas and Refining industries to remove sulfur from natural gas and refined products, including gasoline, jet fuel, diesel fuel, fuel oil, and naphtha.